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Equations 2-138 and 2-139 apply only to systems containing stoichiometric numbers of the two different functional groups. For nonequivalent numbers of the functional groups, the average functionality calculated from Eq. 2-134 is too high. Thus, consider the extreme example of a mixture of 1 mol of glycerol and 5 mol of phthalic acid. Using Eq. 2-134, one calculates a value of 13 or 2.17 for favg. This indicates that a high polymer will be obtained. 6 Further, one would predict from Eq. 2-139 that crosslinking will occur at pc 0:922. Both of these conclusions are grossly in error. It is apparent from previous discussions (Sec. 2-6) that the gross stoichiometric imbalance between the A and B functional groups in this system (r 0:3) precludes the formation of any but extremely low-molecular-weight species. The polymerization will stop with the large portion of the acid functional groups being unreacted. The average functionality of nonstoichiometric mixtures has been deduced [Pinner, 1956] as being equal to twice the total number of functional groups that are not in excess divided by the total number of all molecules present. This simply takes into account the fact that the extent of polymerization (and crosslinking, if it can occur) depends on the de cient reactant. The excess of the other reactant is not useful; in fact, it results in a lowering of the functionality of the system. For the above nonstoichiometric mixture of 1 mol of glycerol and 5 mol of phthalic acid, the favg value is correctly calculated as 6/6 or 1.00. This low value of favg is indicative of the low degree of polymerization that will occur in the system. convert image to pdf in java using itext PDFbox - not able to write images in pdf | Adobe Community - Adobe ...
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asp.net pdf editor component I have solved this with the following code: PDDocument document = new PDDocument(); InputStream in = new FileInputStream(someImage); BufferedImage ... how to open pdf file on button click in mvc In a similar manner the average functionality of nonstoichiometric mixtures containing more than two monomers has been obtained. Consider a ternary mixture of NA moles of AfA , NC moles of AfC , and NB moles of BfB with functionalities fA , fC , and fB , respectively. In this system AfA and AfC contain the same functional groups (i.e., A groups) and the total number of A functional groups is less than the number of B groups (i.e., B groups are in excess). The average functionality in such a system is given by 12=5 5=6 This document was created by an unregistered ChmMagic, please go to http://wwwbisentercom to register it Thanks favg 2 NA fA NC fC NA NC NB 2-140 1; favg 2rfA fB fC fA fC rrfA fB r 1 r fB fC 2-141 barcode code 39 word, word pdf 417, birt data matrix, word data matrix font, birt code 128, birt report barcode font convert image to pdf in java using itext JPG to PDF in Java · GitHub
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21 Feb 2018 ... Apache PDFBox Convert PDF to Image in Java ... Then we loop over each page and create a BufferedImage . Finally we write the image to disk ... The term r is the ratio of A groups to B groups and has a value equal to or less than unity r is comparable to the previously discussed stoichiometric imbalance The term r is the fraction of all A functional groups that belong to the reactant with f > 2 One can easily show by substitution of different values of r, r, fA , fB , and fC into Eqs 2-139 through 2-143 that crosslinking is accelerated (ie, pc decreases) for systems that contain closer to stoichiometric amounts of A and B functional groups (r closer to 1), systems with larger amounts of polyfunctional reactants (r closer to 1) and systems containing reactants of higher functionality (higher values of fA , fB , and fC ) The Carothers equations and Eq 2-78 overlap but are not equivalent Recall the brief note in Sec 2-6b that Eq. 10 12 This document was created by an unregistered ChmMagic, please go to http://wwwbisentercom to register it Thanks create pdf from images java Apache PDFBox : Insert Image on PDF , Java · GitHub
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